Crosslinking in polysaccharide and protein films and coatings for food contact – a review

Azeredo H. M. C., Waldron K. W.. (2016)

Trends in Food Science & Technology, 52, 109-122


This review is a summary of the main crosslinking agents which have been used for protein and polysaccharide films and coatings, and which may be applied as food contact materials. The study emphasizes the mechanisms of crosslinking agents, the chemical groups involved, conditions for application, advantages and drawbacks, as well as examples of applications for food contact materials. Crosslinking is a promising technique to improve the performance and applicability of protein- and polysaccharide-based food contact materials, especially concerning their water sensitivity, which hinders many of their potential applications as food contact materials. Some aldehydes are very effective as crosslinkers, but they have been avoided in food contact materials because of possible migration of aldehyde residues to food, and less toxic compounds have been studied for those applications, such as phenolic acids, oxidized polysaccharides, and enzymes. Crosslinking techniques may help make protein and polysaccharide-based materials more suitable for large-scale processing and applications in the future.


Trends in Food Science & Technology, 52, 109-122


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